Environmental cracking susceptibility of low alloy steel octg. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Simulated tests have been carried out in simulated solution containing high concentration of chloride, with high hydrogen sulphide partial pressure, at high stress level and at 120 c for 720 hours. The pressure of the hydrogen gas causes localized internal cracks, known as hydrogen induced cracks. Carbon and low alloy steels which are subjected to sour service environments may be susceptible to hydrogen induced cracking hic. Hydrogeninduced cracking an overview sciencedirect topics.
Hydrogen cracking is also named as toe cracking or underbead cracking due to its location of occurrence. Abstract h 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. Hydrogen induced cracking steel features, applications. Corrosionpedia what is hydrogeninduced cracking hic. Hydrogeninduced cracking also referred to as cold cracking, is caused by the diffusion of hydrogen in the crystal lattice of haz near the fusion boundary atomic hydrogen is dispersed throughout the weld material, making it weak in mechanical properties. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. May 19, 2009 hic is prevalent in wet h 2 s environments, which is often known as sour service and such cracking over a prolonged period of time without inspection, will reach a critical point and the steel component i. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. In the presence of water and hydrogen sulfide, atomic hydrogen is produced.
Equivalently, low temperature hydrogen induced cracking was also noticed in inconel 718. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Dear muthukrishnan, i would exclude also hydrogen attack as root cause of the crack formation. Hydrogen induced cracks either follow a linear or stepwise path within the material, hence the term stepwise cracking. Susceptibility to hydrogeninduced cracking of api 5l b and x52ms. European studies on the effect of water composition and ph resulted in these. Sulfide stress cracking mostly occurs in very highly acidic environments. Sep 07, 2009 the methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999. Hydrogen induced cracking hic in the oil and gas industry. Types of corrosion materials selection guide swagelok. Susceptibility to hydrogeninduced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials.
In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogen induced cracking hic, sulphide stress cracking ssc and stressoriented hydrogen induced cracking sohic. This clustering produces pressure in the metal which results in the metal losing ductility, toughness and tensile strength. The presence of hydrogen atoms in a metal degrades some of its mechanical properties, especially its ductility, leading in some cases to embrittlement. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. At high temperature and high hydrogen partial pressure, hydrogen can diffuse into carbon steel alloys. The entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile strength. According to iso 15156, hydrogeninduced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Detection, characterization and sizing of hydrogen induced. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. However, under certain stress and material conditions, the cracks can be arranged in a ladderlike array known as stress. The nace specification defines the scc as the cracking of metal involving corrosion and stress both residual and or applied in the presence of h2s and water. Roles of microalloying elements in hydrogen induced. This process is known as hydrogen embrittlement or hydrogeninduced cracking.
Hydrogen induced cracking hic remains a prominent issue for oil and gas exploration in. Adsorbed hydrogen species recombine to form hydrogen molecules, creating pressure from within the metal. According to iso 15156, hydrogen induced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. In susceptible alloys, the hydrogen combines with carbon within the alloy and forms methane. Aug 02, 2014 the entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile strength. Effects of h2s partial pressure and ph of test solution on the hydrogen induced cracking of linepipe steels wan keun kim, seong ung koh, kyoo young kim, boo young yang, ki bong kang dept.
Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. For hydrogen induced cracking to take place, individual hydrogen atoms must cluster at the surface of the metal to create hydrogen molecules. H2s partial pressures and the lowest ph values aqueous medium acidities. Sulfide stress cracking an overview sciencedirect topics. In the case of hydrogen induced corrosion cracking occurs see also corrosion cracking with stress corrosion cracking.
Plates of high strength, low alloy hsla steel jisg3115 spv50q were found to be susceptible to sulfide stress cracking and hydrogen induced cracking hic in wet hsub 2s. Material and metallurgical parameters were investigated. Hydrogen embrittlement of pipelines and remediation mixing with water. The diffusible hydrogen content in the deposited metal significantly increased from 23.
It is often assumed that hic is just a subcategory of sulfide stress cracking. The equilibrium pressure of the molecular hydrogen in the void, which is in contact with the atomic hydrogen in the surrounding metal, is great enough to rupture any metal or alloy. Stress corrosion cracking scc and sulfide stress cracking ssc are the most. Effect of partial pressure of hydrogen on igscc of alloy. Ferritic stainless steels, on the other hand, tend to be fairly resistant to hydrogen stress cracking due to their comparatively low hardness. Element offers hydrogen induced corrosion hic tests to accurately assess the. Detection, characterization and sizing of hydrogen induced cracking in pressure vessels using phased. Hydrogeninduced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking. Material selection for sour service environment pipeline. A comparative study of hydrogeninduced cracking resistances of. A comparative study of hydrogeninduced cracking resistances.
Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Over time, the metal becomes so brittle that it cracks. Susceptibility to hydrogen induced cracking of api 5l b and x52ms lowcarbon steels in nace 177a, 177b, and 284b solutions has been investigated by the present work. Sulfide stress corrosion cracking occurs in presence of hydrogen sulfide. A metallographic analysis of these steels was performed before and after nace tm0284 standard testing. Roles of microalloying elements in hydrogen induced cracking. A method has been developed for determination of the maximum allowed aggressiveness of sour media in pipelines of which the steel has a given susceptibility to hydrogeninduced cracking hic. Corrosion generally involves carbon dioxide co2, sweet corrosion, or hydrogen sulphide h2s, sour corrosion. In the gas phase, a stream is sour if the h2s partial pressure exceeds 0.
Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Abstract as a first step, a literature survey was undertaken on hydrogen induced cracking hic phenomena. Corrosion products were characterized by scanning electron microscopy and xray dispersive energy spectrometry, which were. In the presence of water and hydrogen sulfide, atomic hydrogen is produced and enters the steel, recombining at discontinuities to form molecular gases hydrogen gases. Mechanisms of hydrogen induced cracking in pipeline steels in iom3. Weld metal hydrogen cracking in pipeline girth welds, proc.
Incoloy 825 is superiorly immune to stainless steel grade 316 in the chloride media due to larger content of nickel. Additionally, hydrogen atoms diffuse through metals and coalesce. Past researched about scc of 310s primarily focus on the corrosion mechanism and influence of temperature and corrosive media, but few studies. The methane molecules create a pressure buildup in the metal lattice voids, which leads to embrittlement and even cracking of the metal.
Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Cathodic overpotential and hydrogen partial pressure. In the case of hydrogeninduced corrosion cracking occurs see also corrosion cracking with stress corrosion cracking. Hydrogen stress cracking can affect several different types of metals such as high strength structural, carbon, and low alloy steels, along with titanium, nickel, and aluminium alloys. In ssrts in 5%h 2ar gas, which is the fundamental environment, the relative reduction of area was 1. Processes or conditions involving wet hydrogen sulfide, i.
Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. The hydrogen deleterious effect has a relevant industrial and economic impact being, at the same time, a challenge from the scientific point of view. Gas phase water needs to be there as well even in a trace amount. Cracking results both from the stresses induced by the internal pressure due to the recombination of hydrogen on specific sites in the microstructure, and from the hydrogen embrittling effect, weakening the cohesive forces within the metal. Hydrogen induced cracking hic is most commonly encountered in steels but other metals are susceptible, as shown in table 33. The method is based on standard hic tests and hydrogen permeation experiments, which are correlated to yield a threshold hydrogen concentration below which no cracks will be initiated. Thus hydrogen induced blistering can be seen as a special case of the plane pressure mechanism of hydrogen embrittlement, where high pressure hydrogen forms in. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. Hydrogen embrittlement is mainly a problem in steels with ultimate tensile strength greater than 90 ksi, although a number of additional alloys are susceptible. Acid gas corrosion research at curtin curtin corrosion centre houses state of the art research facilities that can simulate complex operating conditions. Effect of hydrogen partial pressure on the hydrogen. This pressure can increase to levels where the metal has reduced ductility, toughness, and tensile strength, up to the point where it cracks open hydrogeninduced cracking, or hic. From my point of view chlorides from test water cannot be excluded as cause for cl induced scc if the final hydrotest of the vessels has not been performed with demineralized water in case of designs which are not gap free or at least flushed with demineralized water after hydrotest if the.
The frequently reported effect of the partial pressure of hydrogen on the alloy 600 susceptibility to intergranular stress corrosion cracking igscc in hightemperature water is explained in this paper. The diffusion coefficient for the hydrogen atom in the spv50q steel was determined at 2560 c and the activation energy for diffusion was 24. The hydrogen induced cracking hic resistance of several grades of plate steels was. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Crack faces are exposed to a hydrogen gas pressure and hydrogen. Plates of high strength, low alloy hsla steel jisg3115 spv50q were found to be susceptible to sulfide stress cracking and hydrogeninduced cracking hic in wet hsub 2s. Sour gas cracking or sulfide stress cracking at high hydrogen sulfide h 2 s partial pressure sour gas cracking, also known as sulfide stress cracking ssc, is the deterioration of metal due to contact with hydrogen sulfide h 2 s and moisture. Hydrogen induced blister cracking and mechanical failure. However, the test environment of nace tm028496 standard hic test method is unnecessarily severe than that of actual sour service conditions. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Under these operating conditions the predominant failure mechanism is hydrogen cracking, of which there are several types. Critical hydrogen partial pressure in hydrogen embrittlement. Hydrogen induced cracking hic on steel for corrosion. Hydrogen induced cracking hic remains a prominent issue for oil and.
H 2 s gas in the crude oil or natural gas causes hydrogen degradation such as hydrogen induced cracking hic and sulfide stress cracking ssc. Particularly common to the oil and gas industry where the use of steel. The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to. Effects of h2s partial pressure and ph of test solution on. It is a type of hydrogen induced cracking hic in which the primary poison is the evolution of atomic hydrogen. When metal is subjected to tensile stress with high level of hydrogen content, hydrogen induced cracking occurs. Detection of hydrogen induced cracks during inservice. Cosasco provides hydrogen monitoring solutions for corrosion control such as hydrogen blistering hydrogen induced cracking hic on steel. Sandia national laboratories is a multi program laboratory managed and operated by sandia corporation, a wholly owned subsidiary of lockheed martin corporation, for the u. May 07, 2019 sulfide stress corrosion cracking occurs in presence of hydrogen sulfide. From my point of view chlorides from test water cannot be excluded as cause for cl induced scc if the final hydrotest of the vessels has not been performed with demineralized water in case of designs which are not gap free or at least flushed with demineralized water after hydrotest if the design is.
Hydrogen induced cracking of hard materials zthe refining industry has had very few cases of hydrogen related cracking in pure hydrogen service. Specifying valves for hydrogen service valve magazine. Hic in welding cold cracking haz cracking moisture n org compounds r primary sources of h. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Stress corrosion cracking behavior of nickel base alloys. Stress corrosion crackingscc is the main corrosion failure mode for 310s stainless steel. Effect of partial pressure of hydrogen on igscc of alloy 600. An electron backscatter diffraction ebsd micrograph of hic induced by laboratory testing of an x52 alloy is shown in fig. Environmental cracking susceptibility of low alloy steel. Hydrogen induced cracking steel features, applications and. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6.
Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Effects of temperature and pressure on stress corrosion. Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. As the concentration levels of hydrogen sulphide increase, sour operating conditions start to prevail i. The literature sources suggested a variety of methodologies that can be used for ffp. Hydrogen induced blister cracking and mechanical failure in. The pressure of the hydrogen gas causes localized internal cracks, known as. Simply put, hydrogen induced cracking damage increases as the level of hydrogen sulphide increases. Hydrogen cracking its causes, costs and future occurrence. Hydrogen embrittlement, also called hydrogen stress cracking or hydrogen induced cracking, is a condition of low ductility in metals resulting from the absorption of hydrogen. Hydrogeninduced cracking hic is still a challenging issue that requires careful.
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